ISSN 2227-2925 (print)
ISSN 2500-1558 (online)
12+
ИЗВЕСТИЯ ВУЗОВ
Прикладная химия и биотехнология

Данный сайт является архивным. Актуальный сайт журнала находится по адресу vuzbiochemi.elpub.ru

СИНТЕЗ ГИБРИДНЫХ КОМПОЗИТОВ ЗОЛЬ-ГЕЛЬ МЕТОДОМ

Бочкарёва С.С.

2016 / Номер 3 [ ХИМИЧЕСКАЯ ТЕХНОЛОГИЯ ]

Представлены сведения о золь-гель технологии формирования гибридных материалов из золей. Определены достоинства метода. Рассмотрены золь-гель процессы с участием кремнийорганических соединений. Проанализирован многолетний опыт отечественных и зарубежных ученых по получению продуктов золь-гель синтеза на основе кремнийорганических мономеров. Описан способ получения органо-неорганических композитов на основе тетраэтоксисилана и азотсодержащих гетероциклических полимерных соединений. Приведен химический состав и некоторые характеристики синтезированных гибридных материалов. Исследованием сорбционной активности композитов подтверждено сохранение функциональных свойств азотистых полиоснований в составе полученных композитов.

Ключевые слова:

золь-гель синтез,гибридные композиты,тетраэтоксисилан,азотсодержащие полимерные соединения,sol-gel synthesis,hybrid composites,tetraethoxysilane,nitrogen-containing polymer compounds

Библиографический список:

  1. Гребенщиков И.В. Поверхностные свойства стекла // Строение стекла / Под ред. Безбородова. М.: Госхимиздат, 1933. С. 101-116.
  2. Андрианов К.А. О механизме образования и превращения кремнийорганических полимеров // Успехи химии. 1955. Т. 24, N 4. С. 430-439.
  3. Воронков М.Г., Шорохов Н.В. Применение растворов строительных материалов // Информационно-технический листок. Строительная промышленность. 1956. N 2. 22 с.
  4. Борисенко А.И., Николаева Л.В. Тонкие стеклоэмалевые и стеклокерамические покрытия. Л.: Наука, 1970. 70 с.
  5. Шевченко В.Я. Введение в техническую керамику. М.: Наука, 1993. 113 с.
  6. Фридрихсберг Д.А. Курс коллоидной химии. СПб: Химия, 1995. 399 с.
  7. Brinker C.J., Scherer G.W. Sol-Gel Science. The Physics and Chemistry of Sol-Gel Processing. San Diego: Academic Press, Inc., 1990. 908 p.
  8. Lebedeva O.V., Pozhidaev Yu.N., Shaglaeva N.S., Pozdnyakov A.S., Bochcareva S.S. Polyelectrolytes Based on Nitrogenous Bases // Theoretical Foundations of Chemical Engineering. 2010. Vol. 44, N 5. P. 786-790.
  9. Pinero M., La Rosa-Fox N.D., Erce-Montilla R., Esquivias L. Small angleneutron scattering study of PbS quantum dots synthetic routes via sol-gel // J. Sol-Gel Sci.Tech.2003. Vol. 26, N 1-3. P. 527-531.
  10. Schubert U. Silica-based and transition metal-based inorganic-organic hybrids materials - a comparison // J. Sol-Gel Sci. Tech. 2003. Vol. 26, N 1-3. P.47-55.
  11. Honma I., Nakajima H., Nishikawa O., Sugimoto Т., Nomura S. Organic / inorganic nanocomposites for high temperature proton conducting polymer electrolytes // Solid State Ionics. 2003. Vol. 162-163. P. 237-245.
  12. Fidalgo A., Ilharco L.M. Thikness, morphology and structure of sol-gel hybrid films: I - the role of the precursor solution's ageing // J. Sol-Gel Sci. Tech. 2003. Vol.26, N 1-3. P. 363-367.
  13. Voronkov M.G., Belousova L.I., Pozhidaev Yu.N., Vlasova N.N. Mono- and bis-N-[3-(triorganylsilyl)propyl]guanidines and their derivatives // Russian Journal of General Chemistry. 2003. Vol. 73, N 8. P. 1239-1242.
  14. Rao M.S., Gray J., Dave B.C. Smart glasses: molecular programming of dynamic responses in organosilica sol-gels // J. Sol-Gel Sci. Tech. 2003. Vol. 26, N 1-3. P. 553-560.
  15. Krakovsky I., Urakawa H., Kajiwara K., Kohjiya S. Time resolved small angle X-ray scattering gel formation kinetic // J. Non-Cryst. Solids. 1998. Vol. 231. P. 31-40.
  16. Липатов Ю.С. Фазоворазделенные взаимопроникающие сетки. Днепропетровск: УПХТУ, 2001. 326 с. (англ.)
  17. Sysel P., Hodzova R., Sindelar V., Brus J. Preparation and characterization of сrosslinked polyimide-poly(dimethylsiloxane)s // Polymer. 2001. Vol. 42. P. 10079-10085.
  18. Brusatin G., Innocanzi P., Guglielmi M. Basic catalyzed synthesis of hybrid sol-gel materials based on 3-glycidoxypropyltrimethoxysilane // J. Sol-Gel Sci. Tech. 2003. Vol. 26, N 1-3. P. 303-306.
  19. Сhang T. С.,Yeh T.F., Yang С. W., Hong Y. S., Wu T. R. Сhain dynamics and stability of the poly(3-methacryloxypropyltrimethoxysilane) - covinylimidazole // Polymer. 2001. Vol. 42, N 2. P. 8565-8570.
  20. Chung C.-M., Lee S.-J., Kim J.-C., Jang D.-O. Organic-inorganic hybrids based on unsaturated polyеster // J. Non-Cryst. Solids. 2002. Vol. 311, N 2. P. 195-198.
  21. Слинякова И.Б., Денисова Т.И. Кремнийорганические адсорбенты. Получение, свойства, применение. Киев: Наукова думка, 1988. 192 с.
  22. Воронков М.Г., Жагата Л.А. Исследования в области алкоксисиланов. Кинетика и механизм кислотного катализа тетраэтоксисиланов // Изв. АН Латв. ССР. Серия химическая. 1967. N 4. С. 452-460.
  23. Айлер Р.К. Коллоидная химия кремнезема и силикатов. М.: Госстройиздат. 1959. 228 с.
  24. Vlasova N.N., Pozhidaev Yu.N., Raspopina O.Yu., Belousova L.I., Voronkov M.G. Polyorganylsilsesquioxanes containing carbofunctional groups (NH)2C(SO2). Synthesis and sorption properties // Russian Journal of General Chemistry. 1999. Vol. 69. N 9.P. 1391-1394.
  25. Воронков М.Г., Кухарская Э.В., Макарская В.М. Повышение химической и термической устойчивости стекловолокна путем поверхностного модифицирования полиэтоксиэлементосилоксанами // Журнал прикл. химии. 1983. Т. 52, N 4. С. 868-873.
  26. Lenza R.F.S., Vasconcelos W.L. Synthesis and properties of microporous sol-gel silica membranes // J. Non-Cryst. Solids. 2000. Vol. 273, N 1-3. C. 164-169.
  27. Vacassy R., Flatt R.J., Hofmann H., Choi K.S., Singh R.K. Synthesis of microporous silica spheres // J. Colloid and Interface Sci. 2000. Vol. 227, N 2. P. 302-315.
  28. Kimoto M., Hioki A., Sakurai Y., Shiozaki H. Synthesis of micro-particles of silicon dioxide in oksipropilcellulose solutions. 1. The influence of solvent and the molecular weight of oksipropilcellulozy on the growth and morphology of micro-particles//J. Adhes. Soc. Jap. 2003. Vol. 39, N. 10. P. 371-376.
  29. Mokoena E.M., Datye A.K., Coville N.J. A Systematic Study of the Use of DL-Tartaric acid in the Synthesis of Silica Material Obtained by Sol-Gel Method // J. Sol-Gel Sci. Tech. 2003. Vol. 28. P. 307-317.
  30. Lo D., Lam S.K., Ye C., Lam K.S. Narrow line width operation of solid dye laser based on sol-gel silica // Optics Communications. 1998. Vol. 156. P. 316-320.
  31. Niznansky D., Rehspriger J.L. Infrared study of SiO2 sol to gel evolution and gel aging // J. Non-Cryst. Solids. 1995. Vol. 180. P. 191-196.
  32. Tian D., Blachtr S., Jerome R. Biodegradable and biocompatible inorganic-organic hybrid materials: 4. Effect of acid content and water content on the incorporation of aliphatic polyesters into silica by sol-gel process // Polymer. 1999. Vol. 40. P. 951-957.
  33. Messori M., Toselli M., Pilati M., Fabbri E., Fabbri P., Busoli S., Pasquali L., Nannorone S. Flame retarding poly(methylmethacrylate) with nanostructured organic-inorganic hybrid coatings // Polymer. 2003. Vol. 44. P. 4463-4470.
  34. Tadanada K., Tezuka T., Matsuda A., Hayasi A., Tatsumisado M. Utilization of glass paper as a support of proton conductive inorganic-organic hybrid membranes based on 3-glycidoxypropyltrimеthoxysilane // Electrochem. Communication. 2005. Vol. 7. P. 245-248.
  35. Ogura K., Nakaoka K., Nakayama K., Kobayashi M., Fujii A. Thermogravimetriy/mass spectrometry of urease-immobilized sol-gel silica and the application of such a urease-modified electrode to the potentiometric determination of urea // Analytical Chеmica Acta. 1999. Vol. 384. P. 219-225.
  36. Meng Q.G., Fu L.S., Zhang H.J., Lin J., Zheng Y.X., Li H.R., Wang S.B., Yu Y.N. Preparation and characterization of novel luminescent sol-gel films containing a RE3+ carboxylic acid complex // J. Sol-Gel Sci. Tech. 2002. Vol. 24. P. 131-137.
  37. Smarsly B., Garnweitner G., Assink R., Brinkers C.J. Preparation and characterization of mesostructured polymers-functionalized sol-gel-derived thin films // Progress in Organic Coating. 2003. Vol. 47. P. 393-400.
  38. Neoh K.G., Tan K.K., Goh P.L., Huang S.W., Kang E.T., Tan K.L. Electroactive polymer-SiO2 nanocomposites for metal uptake // Polymer. 1999. Vol. 40. P. 887-893.
  39. He J.-P., Li H.-M., Wang X.-Y., Gao Y. In situ preparation of poly(ethylene terephthalate)-SiO2nanocomposites // Eur. Polymer J. 2006. Vol. 42, N 5. P. 1128-1134.
  40. Javaid A., Hughey M. P., Varutbangkul V. et al. Solubility-based gas separation with oligomer-modified inorganic membranes // J. Membrane Science. 2001. Vol. 187, Iss. 1-2. P. 141-150.
  41. Nagale M., Kim B. Y., Bruening M. L. Ultrathin, Hyper branched Poly(acrylic acid) Membranes on Porous Alumina Supports // J. Am. Chem. Soc. 2000. Vol. 122. P.11670-11678.
  42. Qiu F., Zhou Y., Liu J. The synthesis and characteristic study of 6FDA-6FHP-NLO polyimide/SiO2 nanohybrid materials // Eur. Polymer J. 2004. Vol. 40, № 4. P. 713-720.
  43. Sengupta R., Bandyopadhyay A., Sabharwal S., Chaki T. K., Bhowmick A. K. Polyamide-6,6/in situ silica hybrid nanocomposites by sol-gel technique: synthesis, characterization and properties // Polymer. 2005. Vol. 46, N 10. P. 3343-3354.
  44. Kotoky T., Dolui S.K. Synthesis of polystyrene/silica hybrid composites by the sol-gel method: effect of introduction of a flexible component (butylacrylate) into the silylated polystyrene backbone // Colloid and Polymer. Sci. 2006. Vol. 284, N 10. P. 1163-1169.
  45. Li S., Shah A., Hsieh A. J., Haghighat R., Praveen S.S., Mukherjee I., Wei E., Zhang Z., Wei Y. Characterization of poly(2-hydroxyethylmethacrylate-silica) hybrid materials with different silica contents // Polymer. 2007. Vol. 48, N 14. P. 3982-3989.
  46. Ogoshi T., Chujo Y. Synthesis of poly(vinylidene fluoride) (PVdF)/silica hybrids having interpenetrating polymer network structure by using crystallization between PVdF chains // J. Polymer Sci. A. 2005. Vol. 43, N 16. P. 3543-3550.
  47. Capadona L. A., Meador M. A. B., Alunni A., Fabrizio E. F., Vassilaras P., Leventis N. Flexible, low-density polymer crosslinked silica aerogels // Polymer. 2006. Vol. 47, N 16. P. 5754-5761.
  48. Kim M., Choi Y., Park S., Lee J., Lee J. Syntheses and optical properties of hybrid materials containing azobenzene groups via sol-gel process for reversible optical storage // J. Appl. PolymerSci. 2006. Vol. 100, N 6. P. 4811-4848.
  49. Даниловцева Е.И., Анненков В.В., Филина Е.А., Трофимов Б.А. Новые полимерные системы для сорбции металлов // Наука производству. 2003. N 6. С. 44-46.
  50. Лебедева О.В., Пожидаев Ю.Н., Султангареев Р.Г., Поздняков А.С., Бочкарева С.С., Орхокова Е.А., Шаглаева Н.С. Полимерные электролиты на основе винилпиридинов // Журнал прикл. химии. 2009. Т. 82, N 11. С. 1869-1873.
  51. Лебедева О.В., Пожидаев Ю.Н., Шаглаева Н.С., Бочкарева С.С., Еськова Л.А. Сополимеры на основе N-винилпиразола // Журнал прикл. химии. 2011. Т. 84, Вып. 1. С. 128-132.
  52. Пожидаев Ю.Н., Лебедева О.В., Бочкарева С.С., Шаглаева Н.С., Воронков М.Г. Полимерные системы на основе азотистых оснований и кремнийорганических соединений // Перспективные материалы. 2008. Ч. 2, N 6. С. 268-270.
  53. Пожидаев Ю.Н., Лебедева О.В., Бочкарева С.С., Шаглаева Н.С., Поздняков А.С. Полимерные электролиты на основе азотистых оснований // Химическая технология. 2010. Т. 11, N 1. С. 20-25.
  54. Пожидаев Ю.Н., Шаглаева Н.С., Лебедева О.В., Бочкарева С.С., Сафронов А.П., Воронков М.Г. Сополимеры на основе продуктов гидролиза тетраэтоксисилана с поли-N-винилазолами и поливинилпиридинами // Журнал прикл. химии. 2007. Т. 80, N 8. С. 1384-1387.
  55. Шаглаева Н.С., Лебедева О.В., Пожидаев Ю.Н., Султангареев Р.Г., Бочкарева С.С., Еськова Л.А. Органо-неорганические композиты на основе тетраэтоксисилана и азотистых полиоснований // Журнал физической химии. 2007. Т. 81, N 3. С. 406-409.
  56. Pozhidaev Y., Lebedeva O., Bochkareva S., Sipkina E. Hybrid composites from silicon materials and nitrogenous heterocyclic polybases // Advanced Science Letters. 2013. Vol. 19, N 1. P. 309-312.
  57. Pozhidaev Yu.N., Lebedeva O.V., Sipkina E.I. Modified carbon sorbents for recovering platinum(IV) // Theoretical Foundations of Chemical Engineering. 2014. Vol. 48, N 4. P. 497-501.
  58. Pozhidaev Yu., Lebedeva O., Sipkina E., Chesnokova A., Ivanov N. Synthesis and Properties of Hybrid Materials for Ion-Exchange and Complexing Membranes // Advanced Materials Research. 2013. Vol. 749. P. 283-288.
  59. Pozhidaev Yu.N., Lebedeva O.V. Hybrid composites based on 3-aminopropyltriethoxysilane and nitrogen polybases // Russian Journal of Applied Chemistry. 2012. Vol. 85, N 2. P. 244-247.
  60. Grebenshchikov I.V. Surface properties of glass. In: Stroenie stekla [Structure of glass]. Moscow, Goskhimizdat Publ., 1933, pp. 101-116. (in Russian)
  61. Andrianov K.A. On the mechanism of formation and transformation of silicone polymers. Uspekhi khimii [Russian Chemical Reviews].1955, vol. 24, no. 4, pp. 430-439. (in Russian)
  62. Voronkov M.G., Shorokhov N.V. The use of building materials. Informatsionno-tekhnicheskiilistok. Stroitel'naya promyshlennost' [Information and technical sheet. The construction industry].1956, no. 2, 22 p. (in Russian)
  63. Borisenko A.I., Nikolaeva L.V. Tonkie stekloemalevye i steklokeramicheskie pokrytiya [Thin vitreous and the glass cover]. Leningrad, Nauka Publ., 1970, 70 p.
  64. Shevchenko V.Ya. Vvedenie v tekhnicheskuyu keramiku [Introduction into technical ceramics]. Moscow, Nauka Publ., 1993, 113 p.
  65. Fridrikhsberg D.A. Kurs kolloidnoi khimii [Colloid chemistry]. St. Petersburg, Khimiya Publ., 1995, 399 p.
  66. Brinker C.J., Scherer G.W. Sol-Gel Science. The Physics and Chemistry of Sol-Gel Processing. San Diego, Academic Press Inc., 1990, 908 p.
  67. Lebedeva O.V., Pozhidaev Yu.N., Shaglaeva N.S., Pozdnyakov A.S., Bochkareva S.S. Polyelectrolytes Based on Nitrogenous Bases. Theoretical Foundations of Chemical Engineering. 2010, vol. 44, no. 5, pp. 786-790.
  68. Pinero M., La Rosa-Fox N.D., Erce-Montilla R., Esquivias L. Small angleneutron scattering study of PbS quantum dots synthetic routes via sol-gel. J. Sol-Gel Sci. Tech. 2003, vol. 26, no. 1-3, pp. 527-531.
  69. Schubert U. Silica-based and transition metal-based inorganic-organic hybrids materials - a comparison. J. Sol-Gel Sci. Tech. 2003, vol. 26, no. 1-3, pp. 47-55.
  70. Honma I., Nakajima H., Nishikawa O., Sugimoto T., Nomura S. Organic / inorganic nanocomposites for high temperature proton conducting polymer electrolytes. Solid State Ionics. 2003, vol. 162-163, pp. 237-245.
  71. Fidalgo A., Ilharco L. M. Thikness, morphology and structure of sol-gel hybrid films: I - the role of the precursor solution's ageing. J. Sol-Gel Sci. Tech., 2003, vol. 26, no. 1-3, pp. 363-367.
  72. Voronkov M.G., Belousova L.I., Pozhidaev Yu.N., Vlasova N.N. Mono- and bis-N-[3-(triorganylsilyl)propyl]guanidines and their derivatives. Russian Journal of General Chemistry, 2003, vol. 73, no. 8, pp. 1239-1242.
  73. Rao M. S., Gray J., Dave B. C. Smart glasses: molecular programming of dynamic responses in organosilica sol-gels. J. Sol-Gel Sci. Tech., 2003, vol. 26, no. 1-3, pp. 553-560.
  74. Krakovsky I., Urakawa H., Kajiwara K., Kohjiya S. Time resolved small angle X-ray scattering gel formation kinetic. J. Non-Cryst. Solids. 1998, vol. 231, pp. 31-40.
  75. Lipatov Yu.S. Fazovorazdelennye vzaimopronikayushchie setki [Phase-separated interpenetrating polymer networks]. Dnepropetrovsk, USChTU Publ., 2001, 326 p.
  76. Sysel P., Hodzova R., Sindelar V., Brus J. Preparation and characterization of сrosslinked polyimide-poly(dimethylsiloxane)s. Polymer. 2001, vol. 42, pp. 10079-10085.
  77. Brusatin G., Innocanzi P., Guglielmi M. Basic catalyzed synthesis of hybrid sol-gel materials based on 3-glycidoxypropyltrimethoxysilane. J. Sol-Gel Sci. Tech. 2003, vol. 26, no. 1-3, pp. 303-306.
  78. Сhang T.С., Yeh T.F., Yang С.W., Hong Y.S., Wu T.R. Chain dynamics and stability of the poly(3-methacryloxypropyltrimethoxysilane) - covinylimidazole. Polymer. 2001, vol. 42, no. 2, pp. 8565-8570.
  79. Chung C.M., Lee S.J., Kim J.C., Jang D.O. Organic-inorganic hybrids based on unsaturated polyеster. J. Non-Cryst. Solids. 2002, vol. 311, no. 2, pp. 195-198.
  80. Slinyakova I.B., Denisova T.I. Kremniiorganicheskie adsorbenty. Poluchenie, svoistva, primenenie [Silicone adsorbents. Obtaining, properties, application]. Kiev, Naukova Dumka Publ., 1988, 192 p. (in Russian)
  81. Voronkov M.G., Zhagata L.A. Research in the field of alkoksisilane. Kinetics and mechanism of acid catalysis tetraetoksisilanes. Izv. AN Latv SSR. Seriya khimicheskaya [Proc. Latvia SSR Academy of Sciences. Chemistry]. 1967, no. 4, pp. 452-460. (in Russian)
  82. Ailer R.K. Kolloidnaya khimiya kremnezema i silikatov [Colloid chemistry of silica and silicates]. Moscow, Gosstroiizdat Publ., 1959, 228 p.
  83. Vlasova N.N., Pozhidaev Yu.N., Raspopina O.Yu., Belousova L.I., Voronkov M.G. Polyorganylsilsesquioxanes containing carbofunctional groups (NH)2C(SO2). Synthesis and sorption properties. Russian Journal of General Chemistry. 1999, vol. 69, no 9, pp. 1391-1394.
  84. Voronkov M.G., Kukharskaya E.V., Makarskaya V.M. Increased chemical and thermal stability of glass fiber surface modification by polietoksielementosiloksanes. Zhurnal prikladnoi khimii [Russian Journal of Applied Chemistry]. 1983, vol. 52, no. 4, pp. 868-873. (in Russian)
  85. Lenza R.F.S., Vasconcelos W.L.J. Synthesis and properties of microporous sol-gel silica membranes. Non-Cryst.Solids. 2000, vol. 273, no. 1-3, pp. 164-169.
  86. Vacassy R., Flatt R.J., Hofmann H., Choi, K.S., Singh R.K.J. Synthesis of microporous silica spheres. Colloid and Interface Sci. 2000, vol. 227, no. 2, pp. 302-315.
  87. Kimoto M., Hioki A., Sakurai Y., Shiozaki H.J. Synthesis of micro-particles of silicon dioxide in oksipropilcellulose solutions. 1. The influence of solvent and the molecular weight of oksipropilcellulose on the growth and morphology of micro-particles. Adhes. Soc. Jap. 2003, vol. 39, no. 10, pp. 371-376.
  88. Mokoena E.M., Datye A.K., Coville N. Systematic Study of the Use of DL-Tartaric acid in the Synthesis of Silica Material Obtained by Sol-Gel Method. J. Sol-Gel Sci. Tech., 2003, vol. 28, pp. 307-317.
  89. Lo D., Lam S.K., Ye C., Lam K.S. Narrow line width operation of solid dye laser based on sol-gel silica. Optics Communications, 1998, vol. 156, pp. 316-320.
  90. Niznansky D., Rehspriger J.L. Infrared study of SiO2 sol to gel evolution and gel aging. J. Non-Cryst. Solids, 1995, vol. 180, pp. 191-196.
  91. Niznansky D., Plocek J., Rehspringer J.-L., Vanek P., Micka Z. Preparation and characterization of the nanocomposites SiO2/H-bond hidrogensulphate (hidrogenselenate). J. Sol-Gel Sci. Tech., 2003, vol. 26, pp. 447-451.
  92. Tian D., Blachtr S., Jerome R. Biodegradable and biocompatible inorganic-organic hybrid materials: 4. Effect of acid content and water content on the incorporation of aliphatic polyesters into silica by sol-gel process. Polymer. 1999, vol. 40, pp. 951-957.
  93. Messori M., Toselli M., Pilati M., Fabbri E., Fabbri S., Busoli S., Pasquali L., Nannorone S. Flame retarding poly(methylmethacrylate) with nanostructured organic-inorganic hybrid coatings. Polymer, 2003, vol. 44, pp. 4463-4470.
  94. Tadanada K., Tezuka T., Matsuda A., Hayasi A., Tatsumisado M. Utilization of glass paper as a support of proton conductive inorganic-organic hybrid membranes based on 3-glycidoxypropyltrimеthoxysilane. Electrochem. Communication. 2005, vol. 7, pp. 245-248.
  95. Ogura K., Nakaoka K., Nakayama K., Kobayashi M., Fujii A. Thermogravimetriy/mass spectrometry of urease-immobilized sol-gel silica and the application of such a urease-modified electrode to the potentiometric determination of urea. Analytical Chemica Acta. 1999, vol. 384, pp. 219-225.
  96. Meng Q.G., Fu L.S., Zhang H.J., Lin J., Zheng Y.X., Li H.R., Wang S.B., Yu Y.N. Preparation and characterization of novel luminescent sol-gel films containing a RE3+ carboxylic acid complex. J. Sol-Gel Sci. Tech. 2002, vol. 24, pp. 131-137.
  97. Smarsly B., Garnweitner G., Assink, R., Brinkers C. Preparation and characterization of mesostructured polymers-functionalized sol-gel-derived thin films. J. Progress in Organic Coating. 2003, vol. 47, pp. 393-400.
  98. Neoh K.G., Tan K.K. Goh, P.L., Huang S.W., Kang E.T., Tan K.L. Electroactive polymer-SiO2 nanocomposites for metal uptake. Polymer. 1999, vol. 40, pp. 887-893.
  99. He J.-P., Li H.-M. Wang, X.-Y., Gao Y. In situ preparation of poly(ethylene terephthalate)-SiO2nanocomposites. Eur. Polymer J. 2006, vol. 42, no. 5, pp. 1128-1134.
  100. Javaid A., Hughey M. P., Varutbangkul V. [et al.] J. Membrane Science, 2001, vol. 187, no. 1-2, pp. 141-150.
  101. Nagale M., Kim B.Y., Bruening M.L. Ultrathin, Hyper branched Poly(acrylic acid) Membranes on Porous Alumina Supports. J. Am. Chem. Soc. 2000, vol. 122, pp. 11670-11678.
  102. Qiu F., Zhou Y., Liu J. The synthesis and characteristic study of 6FDA-6FHP-NLO polyimide/SiO2 nanohybrid materials. Eur. Polymer J. 2004, vol. 40, no. 4, pp. 713-720.
  103. Sengupta A., Bandyopadhyay A., Sabharwal S., Chaki T.K., Bhowmick A.K. Polyamide-6,6/in situ silica hybrid nanocomposites by sol-gel technique: synthesis, characterization and properties. Polymer. 2005, vol. 46, no. 10, pp. 3343-3354.
  104. Kotoky T., Dolui S.K. Synthesis of polystyrene/silica hybrid composites by the sol-gel method: effect of introduction of a flexible component (butylacrylate) into the silylated polystyrene backbone. Colloid and Polymer Sci. 2006, vol. 284, no. 10, pp. 1163-1169.
  105. Li S., Shah A. Hsieh A.J., Haghighat R., Praveen S.S., Mukherjee I., Wei E., Zhang Z., Wei Y. Characterization of poly(2-hydroxyethylmethacrylate-silica) hybrid materials with different silica contents. Polymer. 2007, vol. 48, no. 14, pp. 3982-3989.
  106. Ogoshi T., Chujo Y. Synthesis of poly(vinylidene fluoride) (PVdF)/silica hybrids having interpenetrating polymer network structure by using crystallization between PVdF chains. J. Polymer Sci. 2005, vol. 43, no. 16, pp. 3543-3550.
  107. Capadona l.A. Meador M.A.B., Alunni A., Fabrizio E.F., Vassilaras P., LeventisN. Flexible, low-density polymer crosslinked silica aerogels. Polymer. 2006, vol. 47, no. 16, pp. 5754-5761.
  108. Kim M., Choi Y., Park S., Lee J. Syntheses and optical properties of hybrid materials containing azobenzene groups via sol-gel process for reversible optical storage. J. Appl. Polymer Sci. 2006, vol. 100, no. 6, pp. 4811-4848.
  109. Danilovtseva E.I., Annenkov V.V., Filina E.A., Trofimov B.A. New polymer systems for metal sorption. Nauka proizvodstvu [Science production]. 2003, no. 6, pp. 44-46. (in Russian)
  110. Lebedeva O.V., Pozhidaev Yu.N., Sultangareev R.G., Pozdnyakov A.S., Bochkareva S.S., Orkhokova E.A., Shaglaeva N.S. Polymer electrolytes based on vinilpiridines. Zhurnal prikladnoi khimii [Russian Journal of Applied Chemistry]. 2009, vol. 82, no. 11, pp. 1869-1873. (in Russian)
  111. Lebedeva O.V., PozhidaevYu.N., Shaglaeva N.S., Bochkareva S.S., Eskova L.A. Copolymers based on N-vinilpirazole. Zhurnal prikladnoi khimii [Russian Journal of Applied Chemistry]. 2011, vol. 84, no. 1, pp. 128-132.(in Russian)
  112. Pozhidaev Yu.N., Lebedeva O.V., Bochkareva S.S., Shaglaeva N.S., Voronkov M.G. Polymer systems on the basis of the nitrogenous bases and organosilicone compounds. Perspektivnye materialy [Advanced materials]. 2008, vol. 2, no. 6, pp. 268-270. (in Russian)
  113. Pozhidaev Yu.N., Lebedeva O.V., Bochkareva S.S., Shaglaeva N.S., Pozdnyakov A.S. Polymer electrolytes based on nitrogenous bases. Khimicheskaya tekhnologiya [Chemical technology]. 2010, vol. 11, no. 1, pp. 20-25. (in Russian)
  114. Pozhidaev Yu.N., Shaglaeva N.S., Lebedeva O.V., Bochkareva S.S., Safronov A.P., Voronkov M.G. Copolymers based on products of hydrolysis of tetraetoksisilane with poly-N-vinilazoles and polivinilpiridines. Zhurnal prikladnoi khimii [Journal of Applied Chemistry]. 2007, vol. 80, no. 8, pp. 1384-1387. (in Russian)
  115. Shaglaeva N.S., Lebedeva O.V., Pozhidaev Yu.N., Sultangareev R.G., Bochkareva S.S., Es'kova L.A. Organic-inorganic composites based on tetraetoksisilane and nitrogen polibases. Zhurnal fizicheskoi khimii [Journal of Physical Chemistry]. 2007, vol. 81, no. 3, pp. 335-338. (in Russian)
  116. Pozhidaev Y., Lebedeva O., Bochkareva S., Sipkina E. Hybrid composites from silicon materials and nitrogenous heterocyclic polybases. Advanced Science Letters. 2013, vol. 19, no. 1, pp. 309-312.
  117. Pozhidaev Yu.N., Lebedeva O.V., Sipkina E.I. Modified carbon sorbents for recovering platinum(IV). Theoretical Foundations of Chemical Engineering. 2014, vol. 48, no. 4, pp. 497-501.
  118. Pozhidaev Yu., Lebedeva O., Sipkina E., Chesnokova A., Ivanov N. Synthesis and Properties of Hybrid Materials for Ion-Exchange and Complexing Membranes. Advanced Materials Research. 2013, vol. 749, pp. 283-288.
  119. Pozhidaev Yu.N., Lebedeva O.V. Hybrid composites based on 3-aminopropyltriethoxysilane and nitrogen polybases. Russian Journal of Applied Chemistry, 2012, vol. 85, no. 2, pp. 244-247.

Файлы:

Язык
RuEn
Отправить статью
Для отправки статьи перейдите на актуальный сайт журнала.
Количество скачиваний:3952