КАТАЛИТИЧЕСКОЕ ГИДРИРОВАНИЕ С ПЕРЕНОСОМ ВОДОРОДА НА КОЛЛОИДНЫХ НАНОЧАСТИЦАХ РОДИЯ

Ниндакова Лидия Очировна , Бадырова Наталия Моисеевна

2014 / Номер 12(95) 2014 [ Химия и металлургия ]

Гидрирование ацетофенона (АФ) с переносом водорода от 2-пропанола изучено на коллоидных системах, полученных восстановлением комплексов родия в присутствии оптически активных стабилизаторов: диаминовых лигандов, четвертичной соли (-)-N1,N4-дибензилен-2,3-дигидрокси-N1,N1,N4,N4-тетраметилбутан-1,4-диаммоний дихлорида и (-)-цинхонидина. Отношение - модификатор:Rh, концентрации субстрата и катализатора - влияет на избыток энантиомера (иэ) в продуктах реакции.

Ключевые слова:

гидрирование с переносом водорода,наночастицы родия,энантиоселективность,transfer hydrogenation,rhodium nanoparticles,enantioselectivity

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